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Volume XIV in the series "Advances in Electrochemical Sciences and Engineering" provides a valuable overview of this rapidly developing field by focusing on the aspects that drive the research of today and tomorrow. §As such it covers the fundamentals as well as an overview of the most important applications, showing how the latest methods are used in the field, including current spectroscopic methods and computational approaches§Top scientists from different areas, both theoretical and experimental, share their expertise on this hot topic, making it a must-have for many different disciplines, including chemistry, physics, biochemistry, engineering as well as surface and materials science.