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Chimie de l''uranium (VI) l''interface Solution / Min raux

Language FrenchFrench
Book Paperback
Book Chimie de l''uranium (VI)   l''interface Solution / Min raux Annick Froideval
Libristo code: 06938501
Publishers Omniscriptum, February 2018
Cette étude est consacrée ŕ la compréhension de la chimie de l'uranium(VI) ŕ l'interface solution /... Full description
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Cette étude est consacrée ŕ la compréhension de la chimie de l'uranium(VI) ŕ l'interface solution / minéral. Les buts de cette étude sont (i) d'identifier et de caractériser les différentes espčces uranyle de surface, i.e. les différents environnements de coordination des atomes d'uranium en utilisant la spectroscopie de photoélectrons induits par rayons X, la spectroscopie d'absorption X et la spectrofluorimétrie laser résolue en temps, et (ii) de déterminer l'influence du pH, de la concentration initiale de U(VI) en solution et de la concentration en ligands hydroxyle sur la spéciation de surface de U(VI). Cette étude a ainsi permis de caractériser les espčces uranyle de surface sur le quartz et un hydroxyde d'aluminium "amorphe" dans une grande gamme de conditions chimiques favorisant, en solution et en l'absence de minéral, l'hydrolyse de l'ion uranyle et la formation d'espčces hydrolysées soit mononucléaires, soit polynucléaires et/ou colloďdales. Cette étude apporte donc des informations sur l'influence de la chimie de la solution, mais aussi de la phase minérale ŕ son contact sur la nature des espčces uranyle de surface.

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About the book

Full name Chimie de l''uranium (VI) l''interface Solution / Min raux
Language French
Binding Book - Paperback
Date of issue 2018
Number of pages 188
EAN 9786131540042
ISBN 6131540047
Libristo code 06938501
Publishers Omniscriptum
Weight 281
Dimensions 152 x 229 x 11
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